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Acid-catalysed aryl hydroxylation of phenylazopyridines: reaction intermediates, kinetics and mechanism

KS Cheon, RA Cox, SR Keum, E Buncel

文献索引:Cheon, Kap-Soo; Cox, Robin A.; Keum, Sam-Rok; Buncel, Erwin Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 5 p. 1231 - 1239

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被引用次数: 17

摘要

A kinetic and product analysis study of the reactions of the three isomeric phenylazopyridines (PAPys) in aqueous sulfuric acid media (30–97 wt% H2SO4) is reported. The final products obtained from the reaction of 4-(phenylazo) pyridine (4-PAPy) are the hydroxylated product 4-(4-hydroxyphenylazo) pyridine, the reduction products 4- aminophenol and 4-aminopyridine, and a small amount of a dimerized product. 3-( ...