A qualitative study of the effects of various substituents on the silicon atom in cross-coupling reactions of alkenylsilanes has been carried out. In intermolecular competition experiments, the influence of carbon-based groups (methyl, ethyl, isopropyl, tert-butyl, phenyl, and 3, 3, 3- trifluoropropyl) and alkoxy groups (monoethoxydimethyl-, diethoxymethyl-, and triethoxy) on the silicon have been evaluated under activation by two different methods, fluoride (TBAF) ...
[Malkoch, Michael; Thibault, Raymond J.; Drockenmuller, Eric; Messerschmidt, Martin; Voit, Brigitte; Russell, Thomas P.; Hawker, Craig J. Journal of the American Chemical Society, 2005 , vol. 127, # 42 p. 14942 - 14949]
