The Journal of Organic Chemistry

Novel amide-directed hydrocarbonylations and double carbonylation of N-allylamides

I Ojima, Z Zhang

文献索引：Ojima, Iwao; Zhang, Zhaoda Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4422 - 4425

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被引用次数: 46

摘要

Summary: The rhodium-catalyzed hydroformylation and palladium-catalyzed hydroesterification of N-allylamides give isoaldehyde (1) and isoester (5), respectively, with good regioselectivity through chelation control while the rhodium-and C~~ Rh~(CO)~~- catalyzed reactions of an N-methallylamide give a novel double carbonylation product (10) and a pyrrolidine (1 l), respectively, with excellent selectivity.