Aliphatic azo compounds. XVI. Stereoisomerization and homolytic decomposition of cis and trans bridgehead diazenes

M Schmittel, C Ruechardt

文献索引：Schmittel,M.; Rueckhardt,C. Journal of the American Chemical Society, 1987 , vol. 109, p. 2750

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被引用次数: 36

摘要

Abstract: For a large series of bridgehead azo compounds, activation parameters for their homolytic decomposition and their cis-trans isomerization reactions are reported. In addition experimental heats of isomerization were obtained and compared with molecular mechanics calculations. It is concluded from a Bell-Evans-Polanyi plot that, in contrast to a previously made assumption, no change in mechanism within this series of trans-azo ...