A Study of the Electronic Spin??State Crossover in {Fe [HC (3, 4, 5??Me3pz) 3] 2}(BF4) 2

…, MD Smith, F Grandjean, L Rebbouh…

文献索引：Reger, Daniel L.; Elgin, J. Derek; Smith, Mark D.; Grandjean, Fernande; Rebbouh, Leila; Long, Gary J. European Journal of Inorganic Chemistry, 2004 , # 16 p. 3345 - 3352

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被引用次数: 8

摘要

Abstract The synthesis, structural, magnetic, and Mössbauer spectroscopic properties of {Fe [HC (3, 4, 5-Me 3 pz) 3] 2}(BF 4) 2 are reported. The single-crystal X-ray structure results indicate that at 150 K {Fe [HC (3, 4, 5-Me 3 pz) 3] 2}(BF 4) 2 has a structure which is very similar to that observed at 220 K for the trigonally distorted octahedral, high-spin {Fe [HC (3, 5-Me 2 pz) 3] 2}(BF 4) 2 complex. Both the magnetic and Mössbauer spectroscopic results ...