Screening of a library of hemisalen ligands in asymmetric H-transfer: Reduction of aromatic ketones in water

…, D Lambin, O Riant, L Aribi-Zouioueche

文献索引：Boukachabia, Mourad; Vriamont, Nicolas; Lambin, Dominique; Riant, Olivier; Aribi-Zouioueche, Louisa Comptes Rendus Chimie, 2014 , vol. 17, # 5 p. 403 - 412

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摘要

Abstract A library of chiral hemisalen ligands (30) was realized. The ligands were synthesized by the condensation of salicylaldehyde derivatives with amino-alcohols (amino- indanol or substituted amino-ethanol) and characterized. These ligands associated with ruthenium (II) precursors were tested on the asymmetric transfer hydrogenation (ATH) of aromatic ketones by sodium formate in water. The different substituent pattern on the ...