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Tetrahedron letters

Fructose-derived ionic liquids: recyclable homogeneous supports

ST Handy, M Okello

文献索引:Handy, Scott T.; Okello, Maurice Tetrahedron Letters, 2003 , vol. 44, # 46 p. 8399 - 8402

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被引用次数: 62

摘要

A new homogeneous support has been developed that is based on a fructose-derived ionic liquid. It has been applied to the preparation of a series of supported Diels–Alder adducts. The cleavage of these adducts from the ionic liquid has resulted in some interesting observations regarding the base stability of imidazolium cations. Using a transesterification cleavage, the ionic support can be recovered and recycled.