Organosulfur compounds. VI.. alpha.-Phosphoryl sulfoxides. II. Synthesis of. alpha.,. beta.-unsaturated sulfoxides and configurational assignments to geometrical …

M Mikolajczyk, S Grzejszczak…

文献索引：Mikolajczyk,M. et al. Journal of Organic Chemistry, 1975 , vol. 40, # 13 p. 1979 - 1984

全文：HTML全文

被引用次数: 44

摘要

A new synthesis of a,@-unsaturated sulfoxides which involves the reaction of carbonyl compounds with 1-diethylphosphoryl-1-methylsulfinylmethyllithium (4) is described. The reaction was found to be nonstereoselective, mixtures of E and 2 isomers being formed from aldehydes and unsymmetrical ketones. The geometry of mono-and disubstituted vinyl sulfoxides so formed was assigned with the aid of NMR spectroscopic methods (INDOR, ...