“β-cis-SAr effect” on decarbonylation from α, β-unsaturated acyl and aroyl complexes

…, A Ohtaka, M Kinomoto, J Terao, H Kurosawa…

文献索引：Kato, Tomohiro; Kuniyasu, Hitoshi; Kajiura, Takamichi; Minami, Yasunori; Ohtaka, Atsushi; Kinomoto, Masanori; Terao, Jun; Kurosawa, Hideo; Kambe, Nobuaki Chemical Communications, 2006 , # 8 p. 868 - 870

全文：HTML全文

被引用次数: 0

摘要

Revealing how to activate organic compounds in collaboration with metal complexes is one of the most fascinating topics in current chemistry. 1 Now it is well-acknowledged that the coordination of a lone pair of heteroatoms to metals can direct and facilitate various types of reactions represented by the oxidative addition of inert bonds to low-valent transition-metal complexes. 2 Herein we wish to report on a novel type of activation utilizing the coordination of a lone pair on ...