Catalytic deallylation of allyl-and diallylmalonates

D Necas, M Turský, M Kotora

文献索引：Necas, David; Tursky, Matyas; Kotora, Martin Journal of the American Chemical Society, 2004 , vol. 126, # 33 p. 10222 - 10223

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被引用次数: 58

摘要

Substituted allylmalonates undergo the selective CC bond cleavage in the presence of triethylaluminum and a catalytic amount of nickel and ruthenium phosphine complexes, resulting in the loss of the allyl moiety and formation of monosubstituted malonates. Comparison of reactivity of the nickel and ruthenium complexes showed that the use of the former is general with respect to the structure of the substituted allylmalonates, and the ...