Synthesis

Dienolates Derived from Unsaturated Carboxylic Acids in Synthesis. Four-Carbon Annellation of Cycloalkanones; Improved Synthesis of Bicyclo [n. 4.0] alken-2-ones

P Ballester, A García-Raso, R Mestres

文献索引：Ballester, Pablo; Garcia-Raso, Angel; Mestres, Ramon Synthesis, 1985 , # 8 p. 802 - 806

全文：HTML全文

被引用次数: 15

摘要

Bicycl0 [n. 4.0] al| icn-2-ones (8); General Procedure:(ienumlinn 1)/'LiI/riunr Ilir- '1liylmni11'e.'A mixture of lithium (0.56 g. 80 mmol). naphtlutlene (5. l 2 g, 40 mmol). and freshly distilled (from blue bcnzophenonc kctyl) tetrahydrotiuran (40 ml) is allowed to stand under argon in an ultrasonic bath for 10 min at 20 'C. Freshly distilled diethylamine (from Cal- l2: 8.34 ml, 80 mmol) is added dropwise (5 min) and the mixture is allowed to stand in the ...