Bis (pyrrol-2-yl) arylenes from the tandem bidirectional addition of vinyl grignard reagent to aryl diesters

…, SA Perez Guarin, WG Skene, WD Lubell

文献索引：Hansford, Karl A.; Guarin, Sergio Andres Perez; Skene; Lubell, William D. Journal of Organic Chemistry, 2005 , vol. 70, # 20 p. 7996 - 8000

全文：HTML全文

被引用次数: 32

摘要

A practical three-step synthesis of bis (pyrrol-2-yl) arylenes has been accomplished, featuring a copper-catalyzed tandem bidirectional addition of vinylmagnesium bromide to aryldicarboxylates. Spectroscopic and cyclic voltammetric analyses revealed the influence of the central aromatic core and pyrrole substitution pattern on the electrochemical properties of these comonomers.