Chiral synthesis via organoboranes. 13. A highly diastereoselective and enantioselective addition of [(Z)-. gamma.-alkoxyallyl] diisopinocampheylboranes to …

HC Brown, PK Jadhav, KS Bhat

文献索引：Brown, Herbert C.; Jadhav, Prabhakar K.; Bhat, Krishna S. Journal of the American Chemical Society, 1988 , vol. 110, # 5 p. 1535 - 1538

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被引用次数: 193

摘要

Abstract: Isomerically pure [(Z)-y-methoxyallyl] diisopinocampheylboranes [1, prepared from (+)-a-pinene; 2, prepared from (-)-a-pinene] have been prepared from B- methoxydiisopinocampheylborane and lithiated allyl methyl ether. These enantiomeric [(Z) ...