Structure and chemistry of the aldehyde ammonias. 1-Amino-1-alkanols, 2, 4, 6-trialkyl-1, 3, 5-hexahydrotriazines, and N, N-dialkylidene-1, 1-diaminoalkanes

AT Nielsen, RL Atkins, DW Moore, R Scott…

文献索引：Nielsen,A.T. et al. Journal of Organic Chemistry, 1973 , vol. 38, p. 3288 - 3295

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被引用次数: 36

摘要

Reaction of aliphatic aldehydes with 15 M aqueous ammonia at-10 f 15'leads instantly to very unstable, low-melting solids believed to be principally 1-amino-1-alkanol hydrates (la-i). On standing in 15 M aqueous ammonia at 0-5” these solids are converted to 2, 4, 6-trialkyl-1, 3, 5-hexahydrotriazines (2a-h), usually isolated as their low-melting crystalline hydrates. Some of these triazine hydrates are the “aldehyde ammonias” prepared and described by ...