Tetrahedron

Hydrogen abstraction from the isomeric cymenes

A Sulpizio, M Mella, A Albini

文献索引：Sulpizio, A.; Mella, M.; Albini, A. Tetrahedron, 1989 , vol. 45, # 23 p. 7545 - 7552

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被引用次数: 11

摘要

The irradiation of cerium (IV) ammonium nitrate in the presence of ortho, meta and para cymene yields products from attack at the methyl group (the nitrates-these ones in 55 to 69% isolated yield-, the nitro derivatives, and the aldehydes) as well as at the isopropyl group (the acetophenones, not obtained from the ortho isomer), with minimal ring nitration. The formation of bibenzyls on irradiation with t-butyl peroxide of the same substrates is also ...