Recueil des Travaux Chimiques des Pays-Bas

Thermal rearrangement of sulphonylmethylnitrosamides (IVth communication on sulphonylnitrosamides)

TJ De Boer

文献索引：de Boer Recueil des Travaux Chimiques des Pays-Bas, 1954 , vol. 73, p. 677,679

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被引用次数: 13

摘要

Sulphonylnitrosamides, ArS0,N (NO) R, when heated in inert solvents, undergo first order decomposition into nitrogen and alkyl arylsulphonates (ArS0,R). A mechanism involving an intermediate diazosulphonate (ArS0,ON = NR) is proposed. ... When a solution of p-tolylsulphonylmethylnitrosamide in toluene, nitrobenzene, anisole, decalin or chlorobenzene is heated above 95O, a considerable quantity of nitrogen (87-92 % ) is evolved. After removal of the solvent an oil remains, ...