Tetrahedron Letters

Synthesis of unsymmetrical polyfluorinated diaryl sulfides by rhodium-catalyzed aryl exchange reaction

M Arisawa, T Ichikawa, M Yamaguchi

文献索引：Arisawa, Mieko; Ichikawa, Takuya; Yamaguchi, Masahiko Tetrahedron Letters, 2013 , vol. 54, # 32 p. 4327 - 4329

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被引用次数: 2

摘要

RhH (PPh3) 4 and 1, 2-bis (diphenylphosphino) benzene (dppBz) catalyze the aryl exchange reaction of polyfluorinated diaryl sulfides. By employing these catalysts, unsymmetrical polyfluorinated diaryl sulfides are synthesized by the reaction of symmetrical polyfluorinated diaryl sulfides and substituted pentafluorobenzenes in the presence of triisopropylsilane.