Journal of the American Chemical Society

Syntheses with triarylvinylmagnesium bromides. Triarylacrylic acids and the indones derived from them

CF Koelsch

文献索引：Koelsch Journal of the American Chemical Society, 1932 , vol. 54, p. 2487,2490

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被引用次数: 14

摘要

It has been shown recently2 that triphenylvinyl bromide reacts with magnesium to form a Grignard reagent which can be carbonated to give triphenylacrylic acid. The present paper describes the results obtained in simi. lar reactions where certain substituted triphenylvinyl bromides were used Two disubstituted triphenylvinyl bromides were studied: a-phenyI-P, P- di-p-tolylvinyl bromide (I, R= CH3) and a-phenyl-P, p-di-p-anisylvinyl bromide (I, R= OCH3 ...