Several 2, 3-cycloalkeno-5, 6-cycloalkeno-4H-pyran-4-ones, such as 2, 3, 5, 6- bicyclopenteno-4H-pyran-4-one and 1, 2-dihydronaphtho [3, 4-b] cyclopenteno [1, 2-e]-4H- pyran-4-one, were synthesized conveniently by the reaction of a cyclic ketone enamine and