… IN DEN VERBINDUNGEN CH3OCH2CH2N (CH3) PCl2,(CH3) 2NCH2CH2OPCl2,(CH3) 2NCH2CH2N (CH3) P (C6 H5) 2,(CH3) 2NCH2CH2N (CH3) P (C6 H5) Cl …

G Bettermann, D Schomburg…

文献索引：Bettermann, Gerhard; Schomburg, Dietmar; Schmutzler, Reinhard Phosphorus and Sulfur and the Related Elements, 1986 , vol. 28, p. 327 - 336

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被引用次数: 18

摘要

Abstract The reaction of MeOCH2CH2N (Me) SiMe3, Me2NCH2CH2OSiMe3, and Me2NCH2CH2N (Me) SiMe3 with PCl3. PhPCl2, and Ph2PCl was found to proceed with cleavage of the N [sbnd] Si or O [sbnd] Si bond and formation of the phosphorus (III) compounds, 3 to 8. In this series of, in part, novel phosphorus (III) compounds an intramolecular donor-acceptor interaction between NMe2 substituents and phosphorus ...