Kinetics of acid catalyzed decomposition of substituted 1, 3-diphenyl-3-methyltriazenes

P Svoboda, O Pytela, M Večeřa

文献索引：Svoboda, Petr; Pytela, Oldrich; Vecera, Miroslav Collection of Czechoslovak Chemical Communications, 1986 , vol. 51, # 3 p. 553 - 563

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被引用次数: 11

摘要

Abstract Kinetics of the acid catalyzed decomposition of fifteen 1-substituted-1, 3-diphenyl-3- methyltriazenes have been studied in 40% aqueous ethanolic buffers at 25 C. The slope found for the dependence log k obs vs pH of the buffer is not equal to unity, and a method of treating such experimental data is suggested. The reaction constant found (ρ=-3.70) indicates that substituents have similar effects on both protonation and decomposition of ...