Advanced synthesis & catalysis

Synthesis of α??Arylphosphonates using Copper??Catalyzed α??Arylation and Deacylative α??Arylation of β??Ketophosphonates

L Rout, S Regati, CG Zhao

文献索引：Rout, Laxmidhar; Regati, Sridhar; Zhao, Cong-Gui Advanced Synthesis and Catalysis, 2011 , vol. 353, # 18 p. 3340 - 3346

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被引用次数: 10

摘要

Abstract Efficient methods for the direct arylation and deacylative arylation of β- ketophosphonates with iodoarenes in presence of a copper (I) or a copper (II) salt as the catalysts have been developed. The corresponding α-arylphosphonates were obtained in high yields. A tentative mechanism for the deacylative arylation reaction was proposed on the basis of the experimental data.