Concurrent anion⋯ π interactions between a perchlorate ion and two π-acidic aromatic rings, namely pentafluorophenol and 1, 3, 5-triazine

…, A Robertazzi, I Mutikainen, U Turpeinen…

文献索引：Goetz, Rens J.; Robertazzi, Arturo; Mutikainen, Ilpo; Turpeinen, Urho; Gamez, Patrick; Reedijk, Jan Chemical Communications, 2008 , # 29 p. 3384 - 3386

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被引用次数: 38

摘要

In the present study, these two types of π-acidic moieties have been combined within a single molecule to examine its potential joint anion binding properties. The ligand 2-(N,N-di(pyridin- 2-yl))-4-(perfluorophenoxy)-6-phenoxy{1,3,5}triazine (dppftz; Scheme 1) was prepared from 2,4,6-trichloro-{1,3,5}triazine, applying an experimental procedure described earlier (see ESI†). 20 Ligand dppftz possesses a 1,3,5-triazine core bearing three different functional ...