Fluoranthene Derivatives. II. The Reaction of Acenaphthylene with Butadiene Derivatives1

MC Kloetzel, HE Mertel

文献索引：Kloetzel; Mertel Journal of the American Chemical Society, 1950 , vol. 72, p. 4786,4789

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被引用次数: 18

摘要

Summary An empirical rule for the estimation of steric hindrance to addition reactions at a doublybonded aliphatic function is enunciated. If one numbers the atoms in branched compounds starting with the atom of the doubly-bonded function most distant from the chain then the greater the nsmbtw of atoms in the six position the greater the steric hindrance to addition. Applications of this rule to many experimental facts are reviewed. Refinements of ...