Chemistry–A European Journal

From Surface??Inspired Oxovanadium Silsesquioxane Models to Active Catalysts for the Oxidation of Alcohols with O2—The Cinnamic Acid/Metavanadate System

C Ohde, C Limberg

文献索引：Ohde, Christian; Limberg, Christian Chemistry - A European Journal, 2010 , vol. 16, # 23 p. 6892 - 6899

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被引用次数: 19

摘要

Abstract Silsesquioxane dioxovanadate (V) complexes were investigated with respect to their potential as a catalyst for the oxidative dehydrogenation of alcohols with O 2 as an oxidant. The turnover frequencies determined were comparatively low, but during the oxidation of cinnamic alcohol an increase in activity was observed in the course of the process, which was inspected more closely. It turned out that during the oxidation of ...