Reactive intermediates from the photolysis of methylpentaphenyl-and pentamethylphenyldisilane

GW Sluggett, WJ Leigh

文献索引：Sluggett, Gregory W.; Leigh, William J. Journal of the American Chemical Society, 1992 , vol. 114, # 4 p. 1195 - 1201

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被引用次数: 55

摘要

Abstract: The photochemistry of methylpentaphenyldisilane (1) and pentamethylphenyldisilane (7) has been investigated using nanosecond laser flash photolysis techniques. Flash photolysis of 1 with 248-nm light in acetonitrile or isooctane solution gives rise to a complex mixture of transient species. A strongly-absorbing transient with k,-= 490 nm and TQ 1.7 ps (in acetonitrile) has been assigned a 1, 3, 5-(l-sila) triene ...