Tetrahedron letters

La reaction de wittig-horner en milieu heterogene VI1. Selectivite de la reaction sur des composes bifonctionnels

J Villieras, M Rambaud, M Graff

文献索引：Villieras, Jean; Rambaud, Monique; Graff, Micheline Tetrahedron Letters, 1985 , vol. 26, # 1 p. 53 - 56

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被引用次数: 45

摘要

Abstract Heterogenous media of low basicity (K 2 CO 3 or KHCO 3), liquid-liquid or solid- liquid allow the Wittig-Horner reaction of fragile and unprotected aldehydes (hydroxyaldehydes, nitroaldehyde and ketoaldehydes) with excellent yields. The reaction is applied to the synthesis of Royal Jelly acid and Queen Substance of Honey bee.