Reductive addition of polyhalomethanes and their related compounds to aldehydes and 1, 2-elimination of the coupling products in a palladium/aluminum bimetal …

H Tanaka, S Yamashita, M Yamanoue…

文献索引：Tanaka, Hideo; Yamashita, Shiro; Yamanoue, Motoi; Torii, Sigeru Journal of Organic Chemistry, 1989 , vol. 54, # 2 p. 444 - 450

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被引用次数: 45

摘要

1. ylic acids: a-amino acids, 1 and a-chloroacetic acids, ll while the 2-phenyl-1, l- dihaloethenes 4 (R= aryl) are key precursors in the phenylacetic acid synthesis. 12 In this paper, we describe a straightforward access to trihalomethyl carbinols 2 and 1, l- dihaloethenes 4 as well as stereocontrolled syntheses of ethyl trans-and cis-3-(2, 2- dihaloethenyl)-2, 2-dimethylcyclopropanecarboxylates. compounds with chloral in the ...