Analytical chemistry

Absolute configurations of K-region epoxide enantiomers of 3-methylcholanthrene, benz [a] anthracene, and benzo [a] pyrene

HB Weems, M Mushtaq, SK Yang

文献索引：Weems, Henri B.; Mushtaq, Mohammad; Yang, Shen K. Analytical Chemistry, 1987 , vol. 59, # 22 p. 2679 - 2688

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被引用次数: 9

摘要

The absolute conflguratlons of K-region epoxide enantlomers of B-methyichoianthrene, benz [a] anthracene, and benzo [a]-pyrene have been determined via their monomethyl ether derlvatives. Methoxylatlon of each racemic or enantiomeric epoxlde by sodium methoxlde resulted In a pair of monomethyl ether derlvatlves, whlch were separated by normalphase high-performance liquid chromatography (HPLC). The position of the ...