Borylation of Unactivated Aryl Chlorides under Mild Conditions by Using Diisopropylaminoborane as a Borylating Reagent

…, LD Marciasini, M Jousseaume…

文献索引：Guerrand, Helene D. S.; Marciasini, Ludovic D.; Jousseaume, Melissa; Vaultier, Michel; Pucheault, Mathieu Chemistry - A European Journal, 2014 , vol. 20, # 19 p. 5573 - 5579

全文：HTML全文

被引用次数: 11

摘要

Abstract The synthesis of arylboronic ester derivatives from aryl chlorides by using aryl (amino) boranes is described. Palladium-catalyzed coupling between aryl chlorides and diisopropylaminoborane leads to the formation of a C [BOND] B bond under mild conditions. A wide range of functional groups are tolerated, making this method particularly useful for the borylation of functionalized aromatics.