Tetrahedron letters

Electroreductive silylation of activated olefins using a reactive metal anode

…, H Nakahiro, K Sanemitsu, T Hirashima, I Nishiguchi

文献索引：Ohno; Nakahiro; Sanemitsu; Hirashima; Nishiguchi Tetrahedron Letters, 1992 , vol. 33, # 38 p. 5515 - 5516

全文：HTML全文

被引用次数: 19

摘要

Abstract Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me 3 SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.