The Journal of organic chemistry

Generation of a silylethylene-titanium alkoxide complex. a versatile reagent for silylethylation and silylethylidenation of unsaturated compounds

R Mizojiri, H Urabe, F Sato

文献索引：Mizojiri, Ryo; Urabe, Hirokazu; Sato, Fumie Journal of Organic Chemistry, 2000 , vol. 65, # 19 p. 6217 - 6222

全文：HTML全文

被引用次数: 41

摘要

(Trimethylsilyl) ethylene-titanium alkoxide complex (1) was generated from trimethyl (vinyl) silane, Ti (Oi-Pr) 4, and i-PrMgCl as a preformed alkene-titanium complex and reacted with several unsaturated compounds such as aldehyde, imine, other vinylsilane, and acetylene ...