Journal of the American Chemical Society

Studies in the Terpene Series. III. 1 Hydrogen Transfer Reaction During the Dehydration of Terpenic Alcohols

VN Ipatieff, H Pines

文献索引：Ipatieff; Pines Journal of the American Chemical Society, 1944 , vol. 66, p. 1120 Journal of the American Chemical Society, 1945 , vol. 67, p. 1226

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被引用次数: 1

摘要

All of the isomeric hexitols have been reported in crystalline form except L-talitol. The synthesis of crystalline/3-L-altrose from L-ribose by Austin and Humollerj makes this very rare sugar available for the synthesis of its reduction product L-talitol. This step has now been accomplished and L-talitol has been obtained in crystalline form, with melting point 87- 88O and rotation [CY]~ OD-2.9'(water) in agreement with those (mp 86O,[CY]''D+ 3.0 in ...