Journal of Organometallic Chemistry

Reaction of organolithium reagents with α-chlorovinyltrimethylsilanes

RF Cunico, YK Han

文献索引：Cunico,R.F.; Han,Y.-K. Journal of Organometallic Chemistry, 1979 , vol. 174, p. 247 - 262

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被引用次数: 12

摘要

Abstract The reaction of (CH 3) 3 SiC (Cl)= CRR′(R= R′= H; R= H, R′= CH 3; R= R′= CH 3; R= R′= C 6 H 5) with organolithium, reagents was examined. Alkenylsilanes of structure (CH 3) 3 SiCH CH-alkyl were obtained from (CH 3) 3 SiC (Cl) CH 2 and alkyllithium reagents. Substrates with R or R′≠ H inhibited addition of the organolithium species to the double bond and led to products derived from chlorine lithium exchange ( ...