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Nuclear magnetic resonance and mass spectra of organomercury hydrides and deuterides

…, GH Stojak, M Symons, P Teesdale-Spittle

文献索引:Craig, Peter J.; Needham, Michael I.; Ostah, Naaman; Stojak, Grace H.; Symons, Martyn; Teesdale-Spittle, Paul Journal of the Chemical Society - Dalton Transactions, 1996 , # 2 p. 153 - 156

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被引用次数: 13

摘要

A series of new organomercury hydrides, including aromatic and fluoroaromatic compounds, have been characterised by mass and NMR spectroscopy. Unusual features of these compounds included an unusually downfield chemical shift for the Hg–H proton, confirmed by deuterium substitution, and a high value for the 199Hg–H coupling constant. The half-life for dilute solutions of methylmercury hydride was in the region of 1–3 h.