The Journal of Organic Chemistry

Reactions of ketones and related compounds with solid supported phosphoric acid catalyst. III. Scope and mechanisms of phenyl alkyl ketone reactions

FE Juge Jr, A Fry

文献索引：Juge,F.E.; Fry,A. Journal of Organic Chemistry, 1970 , vol. 35, # 6 p. 1876 - 1881

全文：HTML全文

被引用次数: 11

摘要

Rearrangement, condensation, disproportionation, and cyclodehydration reactions of phenyl alkyl ketones occur on solid supported phosphoric acid catalyst with good recovery of products. When the alkyl group is methyl or ethyl, disproportionation of aldol condensation products occurs to yield benzoic acid and fragments which eventually yield indans [lJ1, 3- trimethyl-3-phenylindan(3) or 1, l-dimethylindan, respectively]. When the alkyl group is ...