Manipulating reduction potentials in an artificial safranin cofactor
G Raju, J Capo, BR Lichtenstein, JF Cerda, RL Koder
文献索引：Raju, Gheevarghese; Capo, Joseph; Lichtenstein, Bruce R.; Cerda, Jose F.; Koder, Ronald L. Tetrahedron Letters, 2012 , vol. 53, # 10 p. 1201 - 1203
Safranines hold great promise as artificial flavin-like electron transfer cofactors with tunable properties. We report the design and chemical synthesis of the p-methoxy derivative of safranine O using a new synthetic route based on the Ulmann condensation. Spectroelectrochemical comparison of the purified parent safranine and this derivative demonstrates that the modification increases its two-electron reduction potential by ...
