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Journal of the American Chemical Society

Preparation of Nitro Compounds from Oximes. III. The Synthesis of Nitroalkanes

DC Iffland, TF Yen

文献索引:Iffland; Yen Journal of the American Chemical Society, 1954 , vol. 76, p. 4083

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被引用次数: 32

摘要

Recently this sequence of reactions was examined in this Laboratory in order to determine its generality as an adjunct to existing preparations of nitro compounds. a With alicyclic ketoximes it was found that the alkaline solution of bromine produced a bromonitroso compound which, however, could be oxidized to a bromonitro compound with the aid of concentrated nitric acid. Although the sequence was completed with this additional step, ...