Exploratory study of the intermolecular reactivity of excited diphenylmethyl radicals

JC Scaiano, M Tanner, D Weir

文献索引：Scaiano, J. C.; Tanner, M.; Weir, D. Journal of the American Chemical Society, 1985 , vol. 107, # 15 p. 4396 - 4403

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被引用次数: 209

摘要

Conclusions Substitution of zinc (I1) with cobalt (I1) in bovine erythrocyte SOD provides a derivative which allows isotropically shifted proton signals to be detected. From the'H NMR spectra, it can be guessed that the correlation time T~ experienced by protons relaxed by the copper electron is about the same experienced by protons relaxed by the cobalt electrons, since comparable line widths are observed for protons interacting with either metal ion. In ...