Phosphorylation of alcohols through the acid-catalysed fragmentation of α-oxyiminophosphonates

…, R Karaman, H Leader, A Goldblum

文献索引：Breuer, Eli; Karaman, Rafik; Leader, Haim; Goldblum, Amiram Journal of the Chemical Society, Chemical Communications, 1987 , p. 671 - 672

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被引用次数: 16

摘要

Although a-oxyiminophosphonates are easily accessible from acylphosphonates,z their chemistry had hardly been studied, apart from their reduction to a-aminophosphonates ,2J in spite of the interesting possibilities presented by the proximity of the oxime and phosphoryl functions. In this communication we report that monoesters of woxyiminophosphonic acids ... [eg methyl hydrogen (hidroxyiminobenzyl)phosphonate, (l)] undergo acid-catalysed fragmentation to give a ...