Rate constants for the reactions of C2H5O, i??C3H7O, and n??C3H7O with NO and O2 as a function of temperature

…, A Frenzel, K Imrik, P Devolder

文献索引：Fittschen; Frenzel; Imrik; Devolder International Journal of Chemical Kinetics, 1999 , vol. 31, # 12 p. 860 - 866

全文：HTML全文

被引用次数: 46

摘要

Abstract The rate constants of the reactions of ethoxy (C 2 H 5 O), i-propoxy (iC 3 H 7 O) and n-propoxy (nC 3 H 7 O) radicals with O 2 and NO have been measured as a function of temperature. Radicals have been generated by laser photolysis from the appropriate alkyl nitrite and have been detected by laser-induced fluorescence. The following Arrhenius expressions have been determined: