Tetrahedron

The thermodynamic effect of fluorine as a substituent: Vinylic CF2 and CFH and allylic CF2C

WR Dolbier, KS Medinger, A Greenberg, JF Liebman

文献索引：Dolbier, William R.; Medinger, Karl S.; Greenberg, Arthur; Liebman, Joel F. Tetrahedron, 1982 , vol. 38, # 15 p. 2415 - 2420

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被引用次数: 52

摘要

I2-catalyzed isomerizations of 3-fluoropropene and 3, 3-difluoropropene, and a Cope rearrangement of 1, 1-difluoro-1, 5-hexadiene provide thermodynamic data which allow the determination of a number of important group values for contributions to ΔHof which when combined with those determined in the preceding paper allow the calculations of ΔHof's of most simple F-substituted hydrocarbons:[Cd(F)(H)]=− 38.4,[Cd(F) 2]=− 88.0,[C(F) 2 (C ...