The Journal of Organic Chemistry

Bis (perfluoroalkylsulfonyl) methanes and Related Disulfones

RJ Koshar, RA Mitsch

文献索引：Koshar,R.J.; Mitsch,R.A. Journal of Organic Chemistry, 1973 , vol. 38, p. 3358 - 3363

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被引用次数: 88

摘要

The improved synthesis and chemistry of the acidic bis (perfluoroalkylsulfonyl) methanes, R&3O&HaSO~ lt~, and related disulfones are described. New substituted p-disulfones, eg, olefins, alcohols, and halo disulfones, we provided by various organometallic reactions, alkylations, and halogenations of the methylene disulfones or derivatives. Free-radical reactions of the bromo disulfones, CFaS0zCBrXSOzCF3 (X= Br and H), are also reported.