Aryl amines are traditionally valuable in organic synthesis, pharmaceuticals, and materials science. 1, 2, 3, 4 and 5 The synthesis of arylamines has always been a topic of interest in organic chemistry. 6 In the past years, palladium-catalyzed C–N coupling has received an increased attention. 7 A variety of excellent work has been carried out for this reaction. 8 Lithium bis(trimethylsilyl)amide, 8d lithium amide, 8e zinc bis(hexamethyl-disilazide), 8f and ...