Tetrahedron

Reaction of 1-Chlorovinyl p-Tolyl Sulfoxides with Carbanion of Acetonitrile: A Novel Synthesis of Cyclopentanone Derivatives with Three Consecutive Carbon–Carbon …

T Satoh, H Ota

文献索引：Satoh, Tsuyoshi; Ota, Hiroyuki Tetrahedron, 2000 , vol. 56, # 29 p. 5113 - 5122

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被引用次数: 32

摘要

Treatment of 1-chlorovinyl p-tolyl sulfoxides derived from ketones with cyanomethyllithium gave cyclopentadienyl enaminonitriles in high yields with three consecutive carbon–carbon bond-formations. However, the 1-chlorovinyl p-tolyl sulfoxides derived from aldehydes did