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Journal of fluorine chemistry

Aerosol direct fluorination: direct synthesis of perfluorinated glyme ethers

JL Adcock, ML Cherry

文献索引:Adcock,J.L.; Cherry,M.L. Journal of Fluorine Chemistry, 1985 , vol. 30, p. 343

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被引用次数: 13

摘要

Abstract Aerosol direct fluorination of 1, 2-dimethoxyethane, bis (2-methoxyethyl) ether, triethyleneglycol dimethyl ether, and tetraethyleneglycol dimethyl ether produced the perfluorinated analogs in 36%, 22%, 30% and 15% isolated yields based on total input of hydrocarbon into the reactor. High effluent concentrations in excess of 80% were obtained in all cases indicating that low yields are primarily due to mechanical losses, not ...