The Action of Elementary Fluorine upon Organic Compounds. XXIV. The Jet Fluorination of Hydrogen Cyanide, Cyanogen, Methylamine and Ethylenediamine. …

P Robson, VCR McLoughlin, JB Hynes…

文献索引：Robson,P. et al. Journal of the American Chemical Society, 1961 , vol. 83, p. 5010 - 5015

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被引用次数: 13

摘要

A study has been made of the jet nuorination of HCK,(CNi2, CiiaXH:! and I12SCH2CH2hTH* under awidevariety of operating conditions. Each of these compounds yielded the products CFaNFs,(CF,)* XF,(CFa) aN and CFaN== NCF: in varying amounts, indicating that these fluorinations may have operated, in part at least, through a common mechanism. There were also formed the new compounds NF2CF2CF2'2NF2, CP8NFCHF?, CFINFCF~ CFS and ...