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Stereochemical studies. LXII. The Hofmann-Saytzeff and the syn-anti elimination dichotomy: A relationship between the two phenomena

J Sicher, M Svoboda, M Pankova…

文献索引:Sicher,J. et al. Collection of Czechoslovak Chemical Communications, 1971 , vol. 36, p. 3633 - 3649

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被引用次数: 12

摘要

chlorides (II, X= N (CH3h) and of the corresponding p-toluenesulphonates (I and II, X= OTs) has been studied using five different base-solvent combinations. Quantitative data have been obtained on the contribution of syn-and anti-elimination to the formation of the trialkylated oletins III and V indicating that both the processes may play an important role in dependence on the conditions used. The discovery that the two mechanisms operate in ...