Perfluorozinc aromatics by direct insertion of zinc into C–F or C–Cl bonds

…, VI Krasnov, D Peters, VE Platonov, R Miethchen

文献索引：Miller, Alexey O.; Krasnov, Vyacheslav I.; Peters, Dietmar; Platonov, Vyacheslav E.; Miethchen, Ralf Tetrahedron Letters, 2000 , vol. 41, # 20 p. 3817 - 3819

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被引用次数: 31

摘要

For the first time perfluoroaromatic organozinc compounds were obtained by direct action of zinc on C–F bonds in the presence of metal salts (SnCl2, CuCl2, ZnBr2). The reactions are accelerated by ultrasound. The scope of the method can be extended to polyfluoroaromatics which contain other halogen atoms (Cl) in the aromatic ring.