Chemical research in toxicology

Hypersensitive radical probe studies of chloroperoxidase-catalyzed hydroxylation reactions

PH Toy, M Newcomb, LP Hager

文献索引：Toy, Patrick H.; Newcomb, Martin; Hager, Lowell P. Chemical Research in Toxicology, 1998 , vol. 11, # 7 p. 816 - 823

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被引用次数: 17

摘要

The oxidation of hypersensitive radical probes by chloroperoxidase from Caldariomyces fumago (CPO) was studied in an attempt to “time” a putative radical intermediate. Oxidation of (trans-2-phenylcyclopropyl) methane, previously studied by Zaks and Dodds [Zaks, A., and Dodds, DR (1995) J. Am. Chem. Soc. 115, 10419-10424] was reinvestigated. Unrearranged oxidation products were found as previously reported, and control ...